Derivation of the equation to determine the concentration of carbonic acid components by [DIC] and [H+] (review)
In the previous problem, we derived an equation for the percentage of each carbonic acid component to [DIC] at a given pH. Please prepare paper and pencil and transform the following equation to state [HCO3-] = (function of [DIC] and [H+])
Equation (1) [DIC] = [HCO3-] + [CO32-] + [H2CO3]
Equation (3) K1 = [HCO3-]・[H+]/[H2CO3]
Equation (4) K2 = [CO32-]・[H+]/[HCO3-]
Equation (6) [HCO3-]= ~~ ←(function of [DIC] and [H+])
Substitute this into Equations (3) and (4),
Equation (7) [H2CO3]= ~~ ←(function of [DIC] and [H+])
Equation (8) [CO32-]= ~~ ←(function of [DIC] and [H+])
The result is as such.
The "~~" part should be determined by each of you and written on a piece of paper.
最后修改: 2023年07月18日 星期二 09:50