Several types of water samplers have been invented over time, but the basic structure remains the same in that it consists of a "sampling bottle" that stores seawater and a "lid" that closes the sampling bottle.
The well-known water sampler that has been widely used since the early 20th century is the Nansen bottle, which is made of metal (brass). This device has a mechanism that closes the upper and lower valves when the water sampler is tipped over, and when used in combination with a tipping thermometer*, it was widely used for oceanographic observation because it could simultaneously measure the depth of water sampling and the temperature of the water at the site. Toward the end of the 20th century, as analytical items became more diverse and analytical accuracy improved, improvements were required in water sampling methods. The Nansen sampler, which was made of metal (brass), heavy, and limited in its capacity to collect seawater, was replaced by a newer type of sampler. Currently, the most widely used type is the Niskin bottle, which has both a water sampling bottle and lid made of polyvinyl chloride and is available in a wide range of sizes from 1.2 to 30 liters (Figure 8).